Hot melt adhesive compositions containing a terpene-phenolic resin, ethylene copolymer and alkenyl succinic anhydride

ABSTRACT

Hot melt adhesive compositions are provided which contain (a) about 10-30 weight % of an alkenyl succinic anhydride, (b) abut 20-60 weight % of an ethylene copolymer, and (c) about 10-40 weight % of a tackifying resin which is a terpene-phenolic resin.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation-in-part of our parent application Ser. No. 174,296, filed on July 31, 1980, now abandoned.

The applications identified below disclose and claim compositions similar to those disclosed and claimed herein. The compositions disclosed in these applications differ from the present invention in that the tackifying resin included therein differs from the tackifying resin included in the present invention.

Ser. Nos. 229,401; 229,394; 229,400; 229,389; 229,390; 229,369; 229,351.

Each of the above applications has been filed of even date herewith.

BACKGROUND OF THE INVENTION

Hot melt adhesives frequently are employed to prepare laminated structures by bonding two or more laminae together. While many satisfactory hot melt adhesives are available to the art, the art is constantly seeking new compositions having superior performance, or lower cost, or both.

SUMMARY OF THE INVENTION

The applicants have discovered hot melt adhesive compositions useful in laminating polar laminae together. The hot melt adhesive compositions of the invention contain three essential components. The first is an alkenyl succinic anhydride. The second is an ethylene copolymer. The third is a tackifying resin selected from a class described infra.

DETAILED DESCRIPTION OF THE INVENTION

The compositions of the invention contain about 10-30, preferably 15-25, and more especially about 20 weight % of the alkenyl succinic anhydride. The ethylene copolymer is present in the amount of 20-60, preferably 25-50, and more especially about 40 weight % of the composition. The tackifying resin is included in the compositions in the amount of about 10-40, preferably 15-35, and more especially about 25 weight % of the total composition. In the preferred embodiment of the invention, the three named components constitute the entire composition. Optionally, however, the compositions may contain up to about 20 weight % of additional components. An antioxidant of the type conventionally employed with ethylene polymers desirably is included in the compositions.

The alkenyl succinic anhydrides employed in the compositions of the invention are known compounds of the type described in U.S. Pat. No. 4,158,664, whose descriptions are incorporated herein by reference. These compounds are prepared by heating a high molecular weight alpha-olefin containing about 18 or more carbon atoms with maleic anhydride. Their structure is shown below: ##STR1## In the above formula, R is an alkyl group containing at least 15 carbon atoms. Frequently these compounds are prepared from a mixture of alpha-olefins in which each component contains a minimum of about 18 carbon atoms. In this event, R can be expressed as an average value which seldom will be in excess of 49. Preferably R will have an average value of less than 39.

The ethylene copolymers employed in the compositions of the invention will have polymerized therein at least 40 and preferably at least 60 weight % of ethylene, with the balance of the copolymer being one or more polymerized monomers selected from the group consisting of vinyl acetate, acrylic and methacrylic acid, and alkyl esters of acrylic and methacrylic acid. The preferred copolymers will contain 40-90 weight % ethylene with the balance being vinyl acetate. Where the ethylene copolymer contains an alkyl ester of acrylic or methacrylic acid, the alkyl ester preferably will be a methyl or ethyl ester. The ethylene copolymers preferably will have a melt index in the range of about 0.5-200, preferably 1-100, and more especially about 2-20. Methods for preparing such copolymers are well known in the art and certain of such copolymers are commercially available.

The tackifying resins employed in the compositions of the invention will be a terpene-phenolic resin having a Ring and Ball softening point of about 80°-135° C. as determined by ASTM E-28-58T. The terpene-phenolic resins are known materials described at pages 183 and 184 of the text Organic Coating Technology, Vol. I, by Henry Fleming Payne, John Wiley & Sons, Inc., 1954, Library of Congress Catalog Card Number 54-5971, which description is incorporated herein by reference. Resins of this type are sold under the trade designation Piccofyn.

As noted supra, in addition to the named components described above, the compositions of the invention may contain up to about 20 weight % of additional components. Such additional components typically are wax-like materials which can modify the melt viscosities of the products of the invention. Suitable materials of this type include (1) low molecular weight, liquid polybutylenes in the molecular weight range of from about 600 to 3000; (2) petroleum waxes such as paraffin wax having a melting point of from about 130°-165° F., and microcrystalline wax having a melting point of from about 140°-200° F.; the latter melting points being determined by ASTM method D 127-60; (3) polyethylene greases having a softening point of from about 80°-100° C., and a hardness value, as determined by ASTM method D-1321, of about 60-120; (4) mineral oil; (5) synthetic waxes made by polymerizing carbon monoxide and hydrogen, such as Fischer-Tropsch wax; and (6) atactic propylene polymers.

The compositions of the invention are solids at room temperature, but having melting points and melt viscosities in a range such that they can be readily applied to appropriate substrates using conventionally employed hot melt techniques and equipment. The compositions, depending upon their precise formulation, have ring and ball softening points within a range of approximately 80° to 105° C. The compositions can be formulated to have viscosities, at 400° F., from as low as about 500 cps to as high as 20,000 cps or more.

A suitable procedure for preparing the hot melt adhesive compositions involves placing the tackifying resin and the alkenyl succinic anhydride in a jacketed mixing kettle (or in a jacketed heavy duty mixer of the Baker-Perkins or Day type for compositions having high viscosities) equipped with a stirrer and thereupon raising the temperature to a range of from about 250° to 400° F., and preferably 300° to 350° F. When the initially charged components have melted, stirring is initiated and the ethylene copolymer then is added. Stirring and heating are continued until a smooth, homogeneous mass is obtained. The resulting hot melt adhesive composition is drawn off and may be used immediately in hot pots; or, it may be melt-extruded into rope form or converted into pellets, rods, cylinders, slugs, or billets depending on the equipment which will be subsequently used to apply the hot melt; or, it may be placed in cooling pans and held in bulk form for later use; or it may be granulated or diced.

The hot melt adhesive compositions of the invention give very satisfactory results in preparing laminated structures from laminae prepared from resins such as polyamides, acrylonitrile-butadiene-styrene resins, vinyl chloride resins, and wood. The procedural steps for bonding the laminae together are those commonly employed with other hot melt adhesives. The hot melt adhesive is applied to at least one of the surfaces to be bonded. The assembly of touching surfaces then is placed under at least light pressure and cooled to ambient temperature to solidify and set the adhesive. The application temperature of the adhesive is set at a level such that adequate flow is obtained under the applied pressure to obtain a good bond between the surfaces to be bonded.

The following examples are set forth to illustrate more clearly the principles and practice of the invention. Where parts and percentages are set forth, they are on a weight basis unless otherwise noted. As the examples have been transferred directly from our parent application Ser. No. 174,296, filed on July 31, 1980, they also disclose compositions of the type claimed in our related copending applications referred to supra.

EXAMPLE 1 Part A

Several hot melt adhesive formulations were prepared from (a) an alkenyl succinic anhydride prepared from a C-30+ alpha-olefin* and maleic anhydride by the procedure described in U.S. Pat. No. 4,158,664, (b) a binary copolymer of ethylene and vinyl acetate containing about 18 weight % vinyl acetate and having melt index of 2.5, and (c) a tackifying resin, the chemical identity of which is described in the footnotes to Table I. An antioxidant in the amount of 0.5% of the composition was included in each composition to prevent oxidation. Fine particles of the components first were physically admixed at ambient temperature. The physical admixture then was heated to a temperature of about 160° C. with stirring to provide a homogeneous mixture. The compositions of the products, the melt properties of compositions, and the mechanical properties of the compositions are set forth in Table I.

                  TABLE I                                                          ______________________________________                                         Composition 1-A    1-B    1-C  1-D  1-E  1-F  1-G                              ______________________________________                                         Component                                                                      Ethylene Copolymer                                                                         150    150    150  150  150  150  150                              Alkenyl Succinic                                                               Anhydride   100    100    100  100  100  100  100                              Tackifying Resin                                                               A(1)        150    --     --   --   --   --   --                               Tackifying Resin                                                               B(2)        --     150    --   --   --   --   --                               Tackifying Resin                                                               C(3)        --     --     150  --   --   --   --                               Tackifying Resin                                                               D(4)        --     --     --   150  --   --   --                               Tackifying Resin                                                               E(5)        --     --     --   --   150  --   --                               Tackifying Resin                                                               F(6)        --     --     --   --   --   150  --                               Tackifying Resin                                                               G(7)        --     --     --   --   --   --   150                              Antioxidant 2      2      2    2     2   2    2                                Melt Properties                                                                R&BSP, °C. (8)                                                                      91     92     94   96   92   91   87                               Melt                                                                           Viscosity, cps/10.sup.3                                                        @ 325° F.                                                                           39     41.5   47.5 39.0 44.0 38.0 31.4                             @ 350° F.                                                                           26.6   27.0   31.4 26.8 37.5 24.4 20.0                             @ 375° F.                                                                           16.8   17.0   21.6 18.2 28.0 16.8 14.2                             @ 400° F.                                                                           12.3   12.0   13.5 --   18.8 11.8 10.0                             Mechanical                                                                     Properties                                                                     Tensile @ Yield, psi                                                                       500    939    1367 973  1175 1056 622                              Tensile @ Break,psi                                                                        923    1048   1104 1412 883  1499 764                              % Elongation                                                                               499    332    69   402  87   507  413                              ______________________________________                                          Footnotes to Table I                                                           (1) A glycerol ester of a hydrogenated rosin having an R&BSP of 82.degree      C. sold under the designation Foral 85.                                        (2) An aliphatic resin prepared form a C.sub.5 diolefin having an R&BSP o      100° C. sold under the designation Statac 100.                          (3) A terpene resin having an R&BSP of 100° C. sold under the           designation Piccolyte S100.                                                    (4) A terpenephenolic resin having an R&BSP of 100° C. sold under       the designation Piccofyn A100.                                                 (5) A terpeneurethane resin having an R&BSP of 95° C. sold under        the designation Isoterp 95.                                                    (6) An alphamethylstyrene/vinyl toluene resin having an R&BSP of               75° C. sold under the designation Piccotex 75.                          (7) An aromatic hydrocarbon resin having an R&BSP of 58° C. sold        under the designation Piccovar L60.                                            (8) Ring and Ball softening point.                                       

The mechanical properties of the compositions shown in Table I, particularly the tensile properties, are significantly higher than generally similar commercial hot melt adhesives containing microcrystalline waxes in lieu of the alkenyl succinic anhydrides. To demonstrate the magnitude of these differences, controls corresponding to each of the compositions shown in Table I were prepared. The controls were prepared by replacing the alkenyl succinic anhydride of each composition with an equivalent weight of a micro-crystalline wax which melts at 180° F. The tensile properties of the compositions identified in Table I and the controls corresponding thereto are shown in Table II.

                  TABLE II                                                         ______________________________________                                                        Tensile @    Tensile @                                          Property       Yield, psi   Break, psi                                         ______________________________________                                         Resin                                                                          1-A            500          923                                                1-A Control    598          645                                                1-B            939          1048                                               1-B Control    781          705                                                1-C            1376         1104                                               1-C Control    933          874                                                1-D            973          1412                                               1-D Control    612          738                                                1-E            1175         883                                                1-E Control    915          894                                                1-F            1056         1499                                               1-F Control    798          704                                                1-G            622          764                                                1-G Control    520          491                                                ______________________________________                                    

EXAMPLE 2

Laminates were prepared by bonding together sheets of a commercially available ABS resin, a PVC resin, and a nylon resin with adhesive compositions 1A, 1D, 1E, and 1G shown in Table I. In each case, the hot melt adhesive was applied to one surface in an amount to provide substantially 230 grams of adhesive per one square meters of glue line. The adhesive was applied at 400° F. using a Minimatic 400 gun. After the adhesive was applied, the assembly was maintained under a pressure of about 0.5 psi until the assembly cooled to ambient temperature.

Lap shear tensile values were determined on the laminates and the type of failure was noted. The results are shown in Table III, with the type of failure being indicated by the capital letters shown within parentheses following each reported lap shear tensile value. The meanings of the letter designations are:

(A)--Denotes total adhesion failure with the entire adhesive layer remaining on one lamina.

(M)--Denotes mixed adhesion failure in which some of the adhesive layer remains on both laminae.

(C)--Denotes cohesive failure in which both of the laminae, at the glue line, are covered with adhesive. This type of failure indicates that the bond between the adhesive and the laminae is higher than the bulk strength of the adhesive material.

(S)--Denotes failure of the laminae substrates with the adhesive bond remaining intact and unbroken.

                  TABLE III                                                        ______________________________________                                         Adhesive  1-A       1-D       1-E     1-G                                      ______________________________________                                         Laminate                                                                       Pair                                                                           ABS/ABS   410(S)    165(A)    --      405(S)                                             402(M)    325(A)    --      345(A)                                   PVC/PVC   200(M)    120(A)    328(A)  --                                                 335(M)    188(A)    310(A)  --                                       Nylon/Nylon                                                                              345(A)    235(A)    --      365(A)                                             365(M)    --        --      460(A)                                   ______________________________________                                    

EXAMPLE 3

An additional series of hot melt adhesive formulations were prepared following the procedures described in Example 1, Part A. The compositions of this example differed from the compositions shown in Example 1 in that the ethylene copolymer employed was a binary copolymer of ethylene and vinyl acetate containing 40 weight % vinyl acetate and having a melt index of 7.5. The compositions of the products, the melt properties of the compositions, and the mechanical properties of the compositions are set forth in Table IV.

                                      TABLE IV                                     __________________________________________________________________________     Composition    2-A                                                                               2-B                                                                               2-C                                                                               2-D                                                                               2-E                                                                               2-F                                                                               2-G                                                                               2-H                                        __________________________________________________________________________     Component                                                                      Ethylene Copolymer                                                                            150                                                                               150                                                                               150                                                                               150                                                                               150                                                                               150                                                                               150                                                                               150                                        Alkenyl Succinic Anhydride                                                                    100                                                                               100                                                                               100                                                                               100                                                                               100                                                                               100                                                                               100                                                                               100                                        Tackifying Resin A (1)                                                                        150                                                                               -- -- -- -- -- -- --                                         Tackifying Resin B (2)                                                                        -- 150                                                                               -- -- -- -- -- --                                         Tackifying Resin C (3)                                                                        -- -- 150                                                                               -- -- -- -- --                                         Tackifying Resin D (4)                                                                        -- -- -- 150                                                                               -- -- -- --                                         Tackifying Resin E (5)                                                                        -- -- -- -- 150                                                                               -- -- --                                         Tackifying Resin F (6)                                                                        -- -- -- -- -- 150                                                                               -- --                                         Tackifying Resin G (7)                                                                        -- -- -- -- -- -- 150                                                                               --                                         Tackifying Resin H (8)                                                                        -- -- -- -- -- -- -- 150                                        Antioxidant    2  2  2  2  2  2  2  2                                          Melt Properties                                                                R&BSP, °C. (9)                                                                         83 89 85 83 83 87 81 92                                         Melt Viscosity, cps/10.sup.3                                                   @ 325° F.                                                                              18.2                                                                              29.0                                                                              31.0                                                                              24.2                                                                              23.2                                                                              23.8                                                                              16.1                                                                              48.0                                       @ 350° F.                                                                              12.0                                                                              18.4                                                                              17.0                                                                              17.0                                                                              15.8                                                                              16.8                                                                              12.8                                                                              32.0                                       @ 375° F.                                                                              8.8                                                                               12.0                                                                              13.5                                                                              9.6                                                                               13.2                                                                              9.8                                                                               8.9                                                                               15.0                                       @ 400° F.                                                                              6.4                                                                               8.4                                                                               9.8                                                                               7.0                                                                               9.2                                                                               7.2                                                                               6.0                                                                               10.0                                       Mechanical Properties                                                          Tensile @ Yield, psi                                                                          371                                                                               600                                                                               621                                                                               386                                                                               558                                                                               399                                                                               323                                                                               1214                                       Tensile @ Break, psi                                                                          1354                                                                              1403                                                                              1531                                                                              997                                                                               1549                                                                              1254                                                                              937                                                                               2437                                       % Elongation   773                                                                               557                                                                               570                                                                               518                                                                               514                                                                               595                                                                               766                                                                               465                                        __________________________________________________________________________      Footnotes to Table IV                                                          (1) Foral 85  See footnote (1) of Table I                                      (2) Statac 100  See footnote (2) of Table I                                    (3) Piccolyte S100  See footnote (3) of Table I                                (4) Piccofyn A100  See footnote (4) of Table I                                 (5) Isoterp 95  See footnote (5) of Table I                                    (6) Piccotex 75  See footnote (6) of Table I                                   (7) Piccovar L60  See footnote (7) of Table I                                  (8) Phenolic resin having an R&BSP of 121-128° C. sold under the        designation CK 2432.                                                           (9) Ring and Ball softening point.                                       

EXAMPLE 4

Laminates were prepared by bonding together sheets of a commercially available ABS resin, a PVC resin, and a nylon resin with adhesive compositions 2-A, 2-B, 2-C, 2-F, and 2-G shown in Table IV. The laminates were prepared in the identical manner described in Example 2. The lap shear tensile values were determined on the laminates and the type of failure was noted. The results are shown in Table V.

                  TABLE V                                                          ______________________________________                                         Adhesive 2-A     2-B     2-C   2-E   2-F   2-G                                 ______________________________________                                         Laminate                                                                       Pair                                                                           ABS/ABS  310(M)  --      --    --    400(A)                                                                               258(A)                                       335(A)  --      --    --    405(A)                                                                               335(A)                              PVC/PVC  300(A)  208(A)  370(A)                                                                               415(A)                                                                               380(A)                                                                               295(A)                                       315(A)  185(A)  280(A)                                                                               415(A)                                                                               362(A)                                                                               342(A)                              Nylon/Nylon                                                                             272(A)  --      --    --    --    --                                           228(A)  --      --    --    --    --                                  ______________________________________                                    

EXAMPLE 5

An additional series of hot melt adhesive formulations were prepared in the same manner as described in Example 1, Part A. The primary difference in the compositions is that the ethylene copolymer employed therein was a binary copolymer of ethylene and vinyl acetate containing about 60 weight % vinyl acetate and having a melt index of 3.5. The compositions of the products, the melt properties of the composition, and the mechanical properties of the composition are set forth in Table VI.

                  TABLE VI                                                         ______________________________________                                         Composition      3-A     3-B     3-C   3-D                                     ______________________________________                                         Component                                                                      Ethylene copolymer                                                                              150     150     150   150                                     Alkenyl Succinic Anhydride                                                                      100     100     100   100                                     Tackifying Resin A (1)                                                                          150     --      --    --                                      Tackifying Resin C (3)                                                                          --      150     --    --                                      Tackifying Resin E (5)                                                                          --      --      150   --                                      Tackifying Resin F (6)                                                                          --      --      --    150                                     Antioxidant      2       2       2     2                                       Melt Properties                                                                R&BSP, °C. (8)                                                                           86      96      102   94                                      Melt Viscosity, cps/10.sup.3                                                   @ 325° F. 24.8    6.8     38.0  21.0                                    @ 350° F. 15.2    3.7     22.4  16.4                                    @ 375° F. 9.8     2.4     13.2  14.4                                    @ 400° F. 7.0     1.2     10.0  11.2                                    Mechanical Properties                                                          Tensile @ Yield, psi                                                                            304     475     929   325                                     Tensile @ Break, psi                                                                            297     335     1999  816                                     % Elongation     970     95      357   453                                     ______________________________________                                          Footnotes to Table VI                                                          (1) Foral 85  See footnote (1) of Table I                                      (3) Piccolyte S100  See footnote (3) of Table I                                (5) Phenolic CK 2432  See footnote (8) of Table IV                             (6) Isoterp 95  See footnote (5) of Table I                                    (8) Ring and Ball softening point                                        

EXAMPLE 6

A series of laminates were prepared from sheets of a commercially available ABS resin, a PVC resin, and a nylon resin with adhesive compositions 3-A, 3-B, and 3-D shown in Table VI. The laminates were prepared in the same manner as described in Example II. Lap shear tensile values were determined on the laminates and the type of failure was noted. The results are shown in Table VII.

                  TABLE VII                                                        ______________________________________                                         Adhesive  3-A           3-B     3-D                                            ______________________________________                                         Laminate                                                                       Pair                                                                           ABS/ABS   325 (A)      147 (AM) 163 (A)                                                  335 (A)      117 (A)  170 (A)                                        PVC/PVC   250 (M)      142      --                                                       260 (M)      175 (AM) --                                             ______________________________________                                    

EXAMPLE 7

Another series of hot melt adhesive formulations were prepared in the manner described in Example 1, Part A. The ethylene copolymer included in the formulations was a binary copolymer of ethylene and methyl acrylate containing about 20 weight % methyl acrylate and having a melt index of 2.0. The compositions of the products, melt properties of the compositions, and the mechanical properties of the compositions are set forth in Table VIII.

                  TABLE VIII                                                       ______________________________________                                         Composition      4-A       4-B      4-C                                        ______________________________________                                         Component                                                                      Ethylene Copolymer                                                                              150       150      150                                        Alkenyl Succinic Anhydride                                                                      100       100      100                                        Tackifying Resin A (1)                                                                          150       --       --                                         Tackifying Resin D (4)                                                                          --        150      --                                         Tackifying Resin E (5)                                                                          --        --       150                                        Antioxidant      2         2        2                                          Melt Properties                                                                R&BSP, °C. (8)                                                                           93        93       95                                         Melt Viscosity, cps/10.sup.3                                                   @ 325° F. 41.5      44.5     35.8                                       @ 350° F. 27.0      28.0     24.6                                       @ 375° F. 18.5      18.5     18.6                                       @ 400° F. 13.0      12.5     11.4                                       Mechanical Properties                                                          Tensile @ Yield, psi                                                                            545       783      887                                        Tensile @ Break, psi                                                                            694       1140     662                                        % Elongation     525       520      155                                        ______________________________________                                          (1) Foral 85  See footnote (1) of Table I                                      (4) Piccofyn A100  See footnote (4) of Table I                                 (5) Piccotex 75  See footnote (6) of Table I                                   (8) Ring and Ball softening point                                        

EXAMPLE 8

Another series of hot melt adhesive formulations were prepared as described in Example 1, Part A. The ethylene copolymer included in the compositions was binary copolymer of ethylene and ethyl acrylate containing about 18% ethyl acrylate and having a melt index of 6.0. The compositions of the product, the melt properties of the compositions, and the mechanical properties of the composition are set forth in Table IX.

                  TABLE IX                                                         ______________________________________                                         Composition      5-A       5-B     5-C                                         ______________________________________                                         Component                                                                      Ethylene Copolymer                                                                              150       150     150                                         Alkenyl Succinic Anhydride                                                                      100       100     100                                         Tackifying Resin A (1)                                                                          150       --      --                                          Tackifying Resin D (4)                                                                          --        150     --                                          Tackifying Resin E (5)                                                                          --        --      150                                         Antioxidant      2         2       2                                           Melt Properties                                                                R&BSP, °C. (8)                                                                           94        92      95                                          Melt Viscosity, cps/10.sup.3                                                   @ 325° F. 25.2      23.6    24.6                                        @ 350° F. 16.8      14.8    16.2                                        @ 375° F. 11.4      10.0    10.8                                        @ 400° F. 8.0       7.0     7.8                                         Mechanical Properties                                                          Tensile @ Yield, psi                                                                            505       595     670                                         Tensile @ Break, psi                                                                            820       700     620                                         % Elongation     605       350     250                                         ______________________________________                                          (1) Foral 85  See footnote (1) of Table I                                      (4) Piccofyn A100  See footnote (4) of Table I                                 (5) Piccotex 75  See footnote (6) of Table I                                   (8) Ring and Ball softening point                                        

EXAMPLE 9

Laminates were prepared by bonding together sheets of a commercially available ABS resin, PVC resin, and a nylon resin employing the techniques described in Example 2. The adhesive compositions employed were 4-B, 5-A, 5-B, and 5-C shown in Tables VIII and IX. Lap shear tensile values were determined on the laminates and the type of failure was noted. The results are shown in Table X.

                  TABLE X                                                          ______________________________________                                         Adhesive  4-B       5-A       5-B     5-C                                      ______________________________________                                         Laminate                                                                       Pair                                                                           ABS/ABS   180 (a)   222 (A)   412 (S) 100(A)                                             270 (A)   242 (A)   310 (A) 150 (A)                                  PVC/PVC   115 (A)   185 (M)   155 (A) 180 (A)                                            170 (A)   292 (M)   132 (A) 175 (A)                                  Nylon/Nylon                                                                              --        --        585 (A) 250 (A)                                            --        --        510 (A) 355 (A)                                  ______________________________________                                     

What is claimed:
 1. A hot melt adhesive composition consisting essentially of:(a) 10-30 weight % of an alkenyl succinic anhydride, (b) 20-60 weight % of an ethylene copolymer, and (c) 10-40 weight % of a tackifying resin;said alkenyl succinic anhydride having the structure: ##STR2## where R is an alkyl group containing at least about 15 carbon atoms; said ethylene copolymer having polymerized therein at least 40 weight % polymerized ethylene and the balance one or more polymerized monomers from the group consisting of vinyl acetate, acrylic and methacrylic acid and alkyl esters of acrylic and methacrylic acid; and said tackifying resin being a terpene-phenolic resin having a Ring and Ball softening point of about 80°-135° C.
 2. A composition of claim 1 containing about 15-25 weight % of the alkenyl succinic anhydride, about 25-50 weight % of the ethylene copolymer, and about 15-35 weight % of the tackifying resin.
 3. A composition of claim 1 in which the ethylene polymer has a melt index of about 1-100.
 4. A composition of claim 1 in which the ethylene copolymer is a binary copolymer of ethylene and vinyl acetate.
 5. A composition of claim 1 in which the ethylene copolymer is a binary copolymer of ethylene and an alkyl ester of acrylic or methacrylic acid.
 6. A composition of claim 2 in which the ethylene copolymer is a binary copolymer of ethylene and vinyl acetate.
 7. A composition of claim 2 in which the ethylene copolymer is a binary copolymer of ethylene and an alkyl ester of acrylic or methacrylic acid.
 8. A composition of claim 3 in which the ethylene copolymer is a binary copolymer of ethylene and vinyl acetate.
 9. A composition of claim 3 in which the ethylene copolymer is a binary copolymer of ethylene and an alkyl ester of acrylic or methacrylic acid. 